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EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > AMMONIA

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  • Overview of the project and objectives: Assessing the contribution of the different N substrates to the primary production process, such as the biogenic silica production and dissolution in the Antarctic sea-ice provides a means to understand the biogeochemical system functioning. In such a semi closed-type system, assess incorporation rates of HCO3-, NO3-, NH4+, SiOH4, BSi dissolution, nitrification, C-release in close-by ice-cores (3 ice-cores dedicated to (i) 13C-assimilation + 15NH4+ uptake rate, (ii) 13C-assimilation + 15NO3- uptake rate and nitrification, (iii) Biogenic silica production and dissolution via 30Si isotope tool) will allow improving the knowledge of system functioning. This is also closely linked to the thematic of iron availability since these experiments are done close to / on the Trace Metal site allowing us to hopefully propose a relatively complete image of biogeochemical activity and relationship with trace metals on this site. Methodology and sampling strategy: Most of the time we worked close to / directly on the Trace Metal site following precautions concerning TM sampling (clean suits etc.). When we worked close to the TM site, precautions were not such important because we don't need the same drastic precautions for our own sampling. We work together because we want to propose a set of data which helps to characterize the system of functioning in close relation with TM availability (for that, sampling location have to be as close as possible). 14C and 13C-incubation experiment intercalibration work were conducted on the Biosite (different place than TM site except for station 7) Incubation experiment samples are analyzed via (1) Elemental Analyzer - Isotope Ratio Mass Spectrometer (EA-IRMS) for carbon and nitrogen (VUB, Brussels, Belgium); (2) High Resolution Inductively Coupled Mass Spectrometer (HR-ICPMS) for silicon (RMCA, Brussels, Belgium).

  • Data were collected during the 1997-1998 austral summer on voyages by the Aurora Australis and Southern Surveyor. Oceanographic processes in the subantarctic region contribute crucially to the physical and biogeochemical aspects of the global climate system. To explore and quantify these contributions, the Antarctic Cooperative Research Centre (CRC) organised the SAZ Project, a multidisciplinary, multiship investigation carried out south of Australia in the austral summer of 1997-1998. Ammonia data were collected by Ros Watson (and provided by Tom Trull), and as of 2012, are unpublished.

  • Oceanographic measurements were collected aboard RV Investigator cruise in1801 (CSIRO voyage designation in2018_v01) from 11th January to 22nd February 2018, along CLIVAR Southern Ocean repeat meridional section SR3, followed by Adelie land shelf stations, small meridional sections along 150E (the south end of CLIVAR section P11S) and 132E, and several stations along CLIVAR zonal section S4. A total of 108 CTD vertical profile stations were taken on the cruise, most to within 14 metres of the bottom. Over 2800 Niskin bottle water samples were collected for the measurement of salinity, dissolved oxygen, nutrients (phosphate, nitrate+nitrite, silicate, ammonia and nitrite), CFC's plus tracers (CFC-11, CFC-12, SF6 and N2O), dissolved inorganic carbon (i.e. TCO2), alkalinity, pH, C13/C14, genomics, HPLC, POC, chlorophyll, radiogenic isotopes, helium, ice nucleation, and Ca/Mg, using a 36 bottle rosette sampler. Full depth current profiles were collected by an LADCP attached to the CTD package. Upper water column current profile data were collected by a ship mounted ADCP (75 kHz). Trace metal rosette and in situ pump deployments were done at some of the CTD stations. Meteorological and water property data were collected by the array of ship's underway sensors. A large assortment of 29 drifting floats was deployed throughout the cruise. A detailed data report is included with the data set, with summary of all CTD data and important data quality information. The data set contains CTD 2dbar averaged data, and Niskin bottle data (core hydrochemistry of salinity, dissolved oxygen and nutrients, plus CFC-11, CFC-12, SF6 and N2O), in text and matlab formats. A WOCE (CCHDO) 'exchange' format version of the data is also available from the CCHDO data centre.

  • Oceanographic measurements were collected aboard RV Investigator cruise in1805 (CSIRO voyage designation in2018_v05) from 16th October to 16th November 2018, along a number of transects across a standing meander of the Antarctic Circumpolar Current between 148o and 156oE. A total of 77 CTD vertical profile stations were taken on the cruise, most to within 12 metres of the bottom. Over 1900 Niskin bottle water samples were collected for the measurement of salinity, dissolved oxygen, nutrients (phosphate, nitrate+nitrite, silicate, ammonium and nitrite), chlorophyll, POC and DOC, and for incubation experiments, using a 36 bottle rosette sampler. Full depth current profiles were collected by an LADCP attached to the CTD package. Upper water column current profile data were collected by a ship mounted ADCP (75 kHz and 150 kHz). Data coverage was increased by additional transects towing a Triaxus towed CTD system. A microstructure profiler was deployed at many of the CTD stations. Meteorological and water property data were collected by the array of ship's underway sensors. An oceanographic mooring was deployed at 55o 32.544’S , 150o 52.332’E, and a series of floats and drifters were deployed. Bathymetry was collected by the ship’s multibeam system. The data set contains CTD 2dbar averaged data, and Niskin bottle data (core hydrochemistry of salinity, dissolved oxygen and nutrients), in text and matlab formats, and a full data report. A WOCE (CCHDO) 'exchange' format version of the data is also available on request.

  • Oceanographic measurements were collected aboard Aurora Australis cruise au1602, voyage 2 2016/2017, from 8th December 2016 to 21st January 2017. The cruise commenced with a Casey resupply, followed by work around the Dalton Polynya/Moscow University Iceshelf, then the Mertz Glacier region, and then around the Ninnis Polynya. 14 stations at the southern end of the SR3 transect were also completed. Ice conditions prevented access to the front of the Totten Glacier. A total of 73 CTD vertical profile stations were taken on the cruise, most to within 12 metres of the bottom (Table 1). Over 800 Niskin bottle water samples were collected for the measurement of salinity, dissolved oxygen, nutrients (phosphate, nitrate+nitrite, silicate, ammonia and nitrite), dissolved inorganic carbon (i.e. TCO2), alkalinity, Th-234, POC, Chla, PAM, HPLC, Nd, Po-210/Pb-210, bacteria, O-18, caesium, and Teflon pollutants, using a 24 bottle rosette sampler. Full depth current profiles were collected by an LADCP attached to the CTD package. Upper water column current profile data were collected by a ship mounted ADCP. Meteorological and water property data were collected by the array of ship's underway sensors. 8 Argo floats were also deployed (Table 13) on the transit from Hobart to Casey. The data set contains CTD dbar data and Niskin bottle data (i.e. core hydrochemistry only - salinity, dissolved oxygen and nutrients). A detailed data report is included, with a description of the data and important data quality information.

  • This data encompasses a set of biochemical parameter (iron, macronutrients, Chlorophyll-a, particulate organic matter and particulate exopolysaccharides) measured within East Antarctic first-year land-fast and pack sea ice from nine stations sampled along the Wilkes Land and King George V Land Coast during austral mid-late summer 2016/17. This dataset supports the manuscript entitled "Iron distribution in East Antarctic summer sea ice: a potential contribution from glacial basal melt." to be submitted to the Journal of Geophysical Research on Jan/2020 by Luis Paulo Duprat and co-authors.

  • Untreated, macerated wastewater effluent has been discharged to the sea at Davis Station since 2005, when the old wastewater treatment infrastructure was removed. This environmental assessment was instigated to guide the choice of the most suitable wastewater treatment facility at Davis. The assessment will support decisions that enable Australia to meet the standards set for the discharge of wastewaters in Antarctica in national legislation (Waste Management Regulations of the Antarctic Treaty Environmental Protection Act - ATEP) and to meet international commitments (the Madrid Protocol) and to meet Australia's aspirations to be a leader in Antarctic environmental protection. The overall objective was to provide environmental information in support of an operational infrastructure project to upgrade wastewater treatment at Davis. This information is required to ensure that the upgrade satisfies national legislation (ATEP/Waste Management Regulations), international commitments (the Madrid Protocol) and maintain the AAD's status as an international leader in environmental management. The specific objectives were to: 1. Wastewater properties: Determine the properties of discharged wastewater (contaminant levels, toxicity, microbiological hazards) as the basis for recommendations on the required level of treatment and provide further consideration of what might constitute adequate dilution and dispersal for discharge to the nearshore marine environment 2. Dispersal and dilution characteristics of marine environment: Assess the dispersing characteristics of the immediate nearshore marine environment in the vicinity of Davis Station to determine whether conditions at the existing site of effluent discharge are adequate to meet the ATEP requirement of initial dilution and rapid dispersal. 3. Environmental impacts: Describe the nature and extent of impacts to the marine environment associated with present wastewater discharge practices at Davis and determine whether wastewater discharge practices have adversely affected the local environment. 4. Evaluate treatment options: Evaluate the different levels of treatment required to mitigate and/or prevent various environmental impacts and reduce environmental risks.

  • Oceanographic measurements were conducted in the Southern Ocean around Heard and McDonald Islands, and in the Prydz Bay region, from January 1992 to March 1992. A total of 168 CTD (conductivity, temperature and depth) vertical profile stations were taken, most to near bottom. Niskin bottle water samples were collected for the measurement of salinity, dissolved oxygen, nutrients (phosphate, nitrate+nitrite, silicate), chlorofluorocarbons, helium, tritium, dissolved inorganic carbon, alkalinity, carbon isotopes, dissolved organic carbon, dimethyl sulphide/dimethyl sulphoniopropionate, iodate/iodide, oxygen 18, primary productivity, and biological parameters, using a 24 bottle rosette sampler. CTD salinity data have been calibrated against bottle samples, although the calibration quality varies over the cruise. CTD salinity accuracies can be summarised as follows: Stations 1-26: no bottle samples; conductivity calibration from later stations applied; accuracy therefore unknown. Stations 27-102: accuracy approximately 0.005 (PSS78). Stations 83-93: residuals a bit lower than surrounding stations: data uncertainty may be slightly increased. Stations 103-111: no bottle samples; conductivity calibration from surrounding stations applied; accuracy therefore unknown. Stations 112-168: significant increase in data scatter; accuracy approximately 0.010 (PSS78). The bottle data file contains salinities and nutrients. Dissolved oxygen data exist only as titration values recorded on the laboratory analysis sheets. The nutrient data show a fair amount of scatter, particularly when looking at the nitrate vs phosphate ratios. These data should be used with caution. Measurement and data processing techniques are described, and a summary of the data are presented in graphical and tabular form. The fields in this dataset are: oceanography ship station number date start time bottom time finish time cruise start position bottom position finish position maximum position bottom depth pressure temperature (T-90) salinity sigma-T specific volume anomaly geopotential anomaly dissolved oxygen fluorescence photosynthetically active radiation niskin bottle number

  • This work was completed as part of the SIPEX - Sea Ice Physics and Ecosystem eXperiment - voyage. Adapted from the SIPEX website: During SIPEX we investigated the biogeochemistry of iron (Fe), including a comprehensive examination of its distribution, speciation (i.e. the different forms of Fe), cycling and its role in fuelling sea ice-based and pelagic algal communities. A major part of this research concentrated on the influence of organic exopolysaccharides (EPS) on Fe solubility and its bio-availability. The distribution of other bioactive trace elements was also examined as a means of fingerprinting the source(s) of Fe, as well as indicating their biological requirements. ######### Data on the small- to medium scale (0.1-1000 m) spatial and temporal distribution of Fe and EPS in sea ice cores, surface snow, brine and underlying seawater were determined in each sampled medium by the interdisciplinary team working on the SIPEX project (AAS 3026) in the East Antarctic sector in September/October 2007. Data include Chlorophyll a, salinity, temperature, sea-ice thickness, ice texture analysis, macro-nutrients (nitrate, phosphate, silicate), oxygen stable isotopes, POC and DOC, EPS, iron. This work was completed as part of AAS (ASAC) project 3026. See the parent metadata record (ASAC_3026) for more information.

  • Oceanographic measurements were conducted in the Subantarctic Zone south of Tasmania in March 1998. A total of 97 CTD vertical profiles were taken. Over 800 Niskin bottle water samples were collected for the measurement of salinity, dissolved oxygen, nutrients (phosphate, nitrate+nitrite, silicate), dissolved inorganic carbon, alkalinity, carbon isotopes, dissolved organic carbon, N2O isotopes, pH, oxygen-18, barium, nitrogen-15, arsenic, ammonia, DMS/P, bacteria, silicon-32, particulate silicon, productivity, ETS, pigments, species counts, cytometry, particulate organic carbon and nitrogen, urea, copper and iron, using a 24 bottle rosette sampler. Four sediment trap moorings were recovered, and two were redeployed. The fields in this dataset are: oceanography ship station number date start time bottom time finish time cruise start position bottom position finish position maximum position bottom depth pressure temperature (T-90) salinity sigma-T specific volume anomaly geopotential anomaly dissolved oxygen fluorescence photosynthetically active radiation